Free-Radical Substitution in Alkanes · seed 1 · A4, ink-friendly. The answer key prints on its own page for grown-ups.
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How a flash of light starts a chain

Science · Chemistry · ages 16-17
Name ______________________   Date ____________
  1. What is a radical?

    • A species with an unpaired electron
    • A stable ion with a full outer shell
    • A molecule that cannot react
  2. What does ultraviolet light do to a chlorine molecule?

    • It joins two molecules together
    • It splits it into two radicals
    • It removes all the electrons
  3. Which step ends a radical chain?

    • Propagation
    • Initiation
    • Termination
  4. Why does one photon lead to many product molecules?

    • Light keeps shining the whole time
    • The chain regenerates its radical
    • Termination creates new radicals
  5. For ethane with chlorine, which is the first propagation step?

    • Cl radical plus C2H6 gives HCl plus an ethyl radical
    • C2H6 plus Cl2 gives two molecules of HCl
    • Ethyl radical plus C2H6 gives butane plus hydrogen
  6. Further substitution can be avoided, so the flask holds pure chloromethane.

    Circle one:   True   False

  7. Why do chlorine radicals from old refrigerants destroy many ozone molecules each?

    • Each radical is regenerated in a chain
    • Ozone molecules break down on their own
    • Termination multiplies radicals
  8. A student writes propagation without any dots and says the steps still balance. What is wrong?

    • Dots are decoration and can be dropped
    • The dots show where the radicals are
    • Dots belong only on stable molecules
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Answer key

For grown-ups. Fold this page away before handing over the rest.

How a flash of light starts a chain W1-mt_QkreYC9e2d-s1

  1. A species with an unpaired electron · A radical carries an unpaired electron and grabs at neighbours.
  2. It splits it into two radicals · Light splits the halogen into two radicals, starting initiation.
  3. Termination · Two radicals pairing removes the chain carriers.
  4. The chain regenerates its radical · The chain feeds itself until two radicals happen to meet.
  5. Cl radical plus C2H6 gives HCl plus an ethyl radical · The chlorine radical takes a hydrogen from ethane, leaving an ethyl radical.
  6. False · Chloromethane substitutes again, so a mixture always builds up.
  7. Each radical is regenerated in a chain · One radical can loop through many ozone molecules before termination.
  8. The dots show where the radicals are · Dots show the unpaired electron that drives the whole chain.
Worksheet · LightMySky