---
title: "pH, Kw and Strong Acids and Bases"
description: "pH is a way of writing a hydrogen ion concentration as a small number using powers of ten. Water ionises a little itself, and that constant links the two ions, which is what makes the pH of an alkali "
canonical: https://lightmysky.com/learn/science/ph-kw-and-strong-acids-and-bases-mt_KJ4yc25Z_l
source: https://lightmysky.com/learn/science/ph-kw-and-strong-acids-and-bases-mt_KJ4yc25Z_l.md
retrieved: 2026-09-12
---

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# pH, Kw and Strong Acids and Bases

pH is a way of writing a hydrogen ion concentration as a small number using powers of ten. Water ionises a little itself, and that constant links the two ions, which is what makes the pH of an alkali calculable.

Subject: Science · Area: Chemistry · Ages 17 to 18
Page: https://lightmysky.com/learn/science/ph-kw-and-strong-acids-and-bases-mt_KJ4yc25Z_l

## Ready when they can

- Calculates pH from the concentration of a strong acid and works backwards from a pH to a concentration
- Explains why a tenfold dilution changes pH by exactly one unit
- Uses the ionic product of water to get the hydrogen ion concentration in a strong alkali
- Explains why Kw changes with temperature and what that does to the pH of pure water

## Lesson: pH, Kw and strong alkalis

pH is a compact way to write a hydrogen ion concentration: pH = -log[H+]. A 0.01 mol per cubic decimetre HCl solution has pH 2, and working backwards, a pH of 3 means [H+] of 0.001 mol per cubic decimetre.

Dilute an acid tenfold and [H+] drops to a tenth of what it was. The log scale turns that tenth into a rise of exactly one pH unit, which makes dilution maths quick.

**Example.** Water itself gives Kw = [H+] times [OH-] = 1.0 x 10-14 at 25 C. In 0.10 mol per cubic decimetre NaOH, [OH-] is 0.10, so [H+] is 1.0 x 10-13 and the pH works out as 13.

**Tip.** Kw grows as water warms, so pure water at 50 degrees has a pH below 7. It is still neutral, because [H+] and [OH-] stay equal to each other.

**Recap.** Logs compress concentrations to pH, Kw links the two ions, and warm pure water sits below pH 7 yet stays neutral.

## Practice

8 questions on this page, each with its working shown.

## Needs first

- [Kp, Partial Pressures and Gas Equilibria](https://lightmysky.com/learn/science/kp-partial-pressures-and-gas-equilibria-mt_1R8BpA2hfK)
- [The Equilibrium Constant Kc](https://lightmysky.com/learn/science/the-equilibrium-constant-kc-mt_3G8b6Hyz3u)
- [Standard Form](https://lightmysky.com/learn/mathematics/standard-form-mt_GbZZ2xjBTt)
- [Zero and Negative Indices](https://lightmysky.com/learn/mathematics/zero-and-negative-indices-mt_jAtXBSVqkj)
- [Logarithms as the Inverse of Exponentials](https://lightmysky.com/learn/mathematics/logarithms-as-the-inverse-of-exponentials-mt_skLQLUan0T)
- [Strong and Weak Acids and the pH Scale](https://lightmysky.com/learn/science/strong-and-weak-acids-and-the-ph-scale-mt_Y4nSn5XH56)

## Opens up

- [Amines and Amides: Basicity and the Nitrogen Functional Groups](https://lightmysky.com/learn/science/amines-and-amides-basicity-and-the-nitrogen-functional-groups-mt_cGP3ZJ8S6h)
- [Weak Acids, Ka and pKa](https://lightmysky.com/learn/science/weak-acids-ka-and-pka-mt_q7fYb7qzMH)
