Solubility Equilibria and When a Precipitate Appears · seed 1 · A4, ink-friendly. The answer key prints on its own page for grown-ups.

Reading the solubility product

Science · Chemistry · ages 17-18
Name ______________________   Date ____________
  1. Two clear solutions are mixed and Q works out bigger than Ksp. What happens?

    • More salt keeps dissolving
    • Nothing changes at all
    • A precipitate forms
  2. What does the solid itself contribute to the Ksp expression?

    • Nothing, the solid is left out
    • Its mass in grams
    • Its volume in liters
  3. At solubility equilibrium, ions still leave and rejoin the solid at equal rates.

    Circle one:   True   False

  4. For magnesium hydroxide the math gives Ksp = 4x cubed. Where do the 4 and the cube come from?

    • The solid counts twice in the expression
    • One magnesium ion and two hydroxide ions per unit
    • Magnesium weighs four times as much
  5. A 1:1 salt has Ksp = 9, so its solubility satisfies x squared = 9. What is x?

    Answer: ______________

  6. Extra chloride is poured into a saturated silver chloride solution. What happens to its solubility?

    • It rises as chloride pulls ions out
    • It falls as equilibrium shifts toward the solid
    • It stays exactly the same
  7. A chemist wants silver out of solution but must leave a second metal dissolved. Which trick helps?

    • Heat until both metals fall together
    • Dilute until Ksp stops applying
    • Add a common ion to drop one metal selectively
  8. Q works out below Ksp, but a student predicts a precipitate anyway. What is the error?

    • Below Ksp means unsaturated, so nothing precipitates
    • Q must be computed before mixing, not after
    • Ksp only applies to 1:1 salts
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Answer key

For grown-ups. Fold this page away before handing over the rest.

Reading the solubility product W1-mt_IMdWLxIAFt-s1

  1. A precipitate forms · Above Ksp the extra ions have nowhere to go but out as solid.
  2. Nothing, the solid is left out · A pure solid counts as constant, so it never appears in Ksp.
  3. True · Equilibrium is balanced motion, not a frozen standstill.
  4. One magnesium ion and two hydroxide ions per unit · Each unit releases one Mg ion and two OH ions, giving x times 2x squared.
  5. 3 · For a 1:1 salt Ksp is x squared, and the square root of 9 is 3.
  6. It falls as equilibrium shifts toward the solid · The common ion drives the balance back toward solid, so less dissolves.
  7. Add a common ion to drop one metal selectively · The common ion effect precipitates one metal while the other stays dissolved.
  8. Below Ksp means unsaturated, so nothing precipitates · Below Ksp the solution can still take more ions, so no solid falls out.
Worksheet · LightMySky