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Time-Dependent Perturbation Theory and Fermi's Golden Rule

A perturbation switched on in time drives transitions between states at a rate set by a matrix element and the density of final states. This is where absorption, emission and decay rates come from.

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What a learner can do afterwards

  • Computes a first-order transition amplitude for a perturbation applied for a finite time
  • States the golden rule and identifies the matrix element and the density of states in a given problem
  • Explains why the rate depends on how many final states are available

1 · Read

A perturbation switched on in time drives transitions between states. To first order, the transition amplitude after a finite time comes from letting the perturbation act and adding up its effect over that window.

For steady rates into many final states, the golden rule applies: the rate is set by a matrix element connecting the states and the density of final states waiting at the right energy. This is where absorption, emission, and decay rates come from.

Try it together

An atom sits excited with empty states below it. The matrix element links the two levels, the density counts how many ways the decay can land, and their combination sets how fast the atom emits.

Good to know

When asked why one decay is faster than another, count the landing places first. More available final states means a faster rate, even when the matrix elements look alike.

Finite-time kicks give amplitudes, the golden rule gives rates, and the rate grows with the matrix element and the crowd of final states.

2 · Watch

Take it off screen

Print a worksheetA4 with an answer key page for grown-ups. No screen, no internet.

Where it sits

Then practise

8 questions wait behind this lesson, each with its answer explained. Every answer feeds the sky: stars light as they are learned, and dim when it is time to come back.

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Time-Dependent Perturbation Theory and Fermi's Golden Rule · Science, ages 23 to 24 · LightMySky