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Period 3 Oxides and the Acid-Base Divide

Metal oxides on the left of period 3 give alkalis with water, non-metal oxides on the right give acids, and aluminium oxide does both. The bonding changes across the row and the reactions follow it.

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What a learner can do afterwards

  • Writes equations for sodium oxide and for sulfur trioxide reacting with water
  • Links the change from ionic to covalent bonding across the row to the change from basic to acidic
  • Explains what amphoteric means using aluminium oxide with acid and with alkali
  • Predicts the approximate pH of the solution a named period 3 oxide makes

1 · Read

The left of the row gives alkalis. Sodium oxide meets water to make sodium hydroxide solution: Na2O plus H2O gives 2NaOH. Magnesium oxide does the same basic job. These oxides are ionic, and their solutions turn alkaline.

The right of the row gives acids. Sulfur trioxide meets water to make sulfuric acid: SO3 plus H2O gives H2SO4. Phosphorus oxides do the same acidic job. These oxides are covalent, and their solutions turn acidic.

Try it together

Aluminium oxide sits on the fence and reacts both ways. It takes on acids to give a salt plus water, and it takes on alkalis to give an aluminate. Oxides that behave like this are called amphoteric.

Good to know

To predict a pH, read the bonding. Metal oxides from the left give pH above 7, non-metal oxides from the right give pH below 7, and aluminium oxide offers no simple pH.

Ionic oxides turn water alkaline, covalent oxides turn it acidic, and aluminium oxide does both.

2 · Watch

Take it off screen

Print a worksheetA4 with an answer key page for grown-ups. No screen, no internet.

Where it sits

Then practise

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Period 3 Oxides and the Acid-Base Divide · Science, ages 16 to 18 · LightMySky